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About a day later, they all die from suffocation rather than being boiled alive. The ocean has boiled away after a few weeks, the sun becomes a Red Giant and literally melted the planet into a liquid metal ball that's hot as 7000 degrees Celsius. In le Pays maudit, Gargamel's hovel soon dissolved awhile the nearest mountain ranges also melt.
Snorkland soon melted into the liquid lava after being burned by the temporary return of Oxygen that came from the remains of liquid water, The sun soon swallowed Mercury and Venus before finally engulfing Earth and it's moon, the star soon began an attempt to fusing Iron after fusing several other Elements from 2 to 25. The Iron steals away the sun's energy and the star implodes in on itself due to the massive gravity, all without making a sound.
Its now over, what remains of the sun is being dispersed out throughout to the galaxy to make new stars. Radio is right, no one on Earth died in vain. Life goes on for the Universe, for now.
This has been an experiment to see what would happen if the Smurfs and Snorks were to face this catastrophe, even without the help of some OC characters the results would be the same. Right now, life is thriving, diversifying, and living. The Smurfs and Snorks live their lives in their environments, under the mercy of the sun. By the time the sun does die, they would be long gone. Right now, it's the best time to be alive.